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Hydrosilylation of the CC triple bond by phenyl- and thienyl-silanes

✍ Scribed by E. Lukevics; R.Ya. Sturkovich; O.A. Pudova


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
392 KB
Volume
292
Category
Article
ISSN
0022-328X

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✍ Miriam Karni; Yitzhak Apeloig; Detlef Schröder; Waltraud Zummack; Roberto Rabezz 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB 👁 2 views

Neutralization of [C,H,Si,X]  .+ radical cations (X=F, Cl) in conjunction with electronic structure calculations provides the first experimental evidence for the formation of the neutral silynes HC≡SiF and HC≡SiCl, which have nonlinear structures (see picture).