Hydrosilylation of Ketone and Imine over Poly-N-Heterocyclic Carbene Particles
✍ Scribed by MeiXuan Tan; Yugen Zhang; Jackie Y. Ying
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 221 KB
- Volume
- 351
- Category
- Article
- ISSN
- 1615-4150
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The dihydride ruthenium N-heterocyclic carbene complex Ru(IMes ) is an efficient catalyst for both direct hydrogenation and transfer hydrogenation of ketones and imines, in the absence of base.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
## Abstract The carbene derived from triazolium salt TRC catalyzes the title reactions to give the corresponding saturated alcohols or (E)‐alkenols, correspondingly, after quenching of the resulting siloxanes with Bu~4~NF.