ChemInform Abstract: N-Heterocyclic Carbene-Catalyzed Hydrosilylation of Styryl and Propargylic Alcohols with Dihydrosilanes.

✍ Scribed by Qiwu Zhao; Dennis P. Curran; Max Malacria; Louis Fensterbank; Jean-Philippe Goddard; Emmanuel Lacote

• Publisher: John Wiley and Sons
• Year: 2011
• Weight: 48 KB
• Volume: 43
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201201057

✦ Synopsis

Abstract

The carbene derived from triazolium salt TRC catalyzes the title reactions to give the corresponding saturated alcohols or (E)‐alkenols, correspondingly, after quenching of the resulting siloxanes with Bu~4~NF.