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Hydrophobicity-induced drying transition in alkanethiol self-assembled monolayer—water interface

✍ Scribed by V. Lakshminarayanan; Ujjal Kumar Sur

Book ID
110644290
Publisher
Springer-Verlag
Year
2003
Tongue
English
Weight
143 KB
Volume
61
Category
Article
ISSN
0304-4289

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Analyses of optical frequency ellipsometric spectra obtained in situ upon completion of the self-assembly of n-alkanethiolate monolayers on gold substrates immersed in methanol reveal the presence of a 1.2 + 0.4 A thick S/Au interface layer. This layer exhibits unique optical transitions, modeled as