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Hydrolytic reactions of carbyl sulfate

✍ Scribed by Wooton, David L.; Lloyd, William G.


Book ID
126334391
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
460 KB
Volume
39
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES


Reactions of Ξ²-sultones and carbyl sulfa
✍ Bert H. Bakker; Ruud M. Schonk; Hans Cerfontain πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 457 KB

## Abstract Ring opening of the octane‐β‐sultones 1a‐c by methanol gives the β‐methoxyoctane‐sulfonic acids 2a‐c by __S__~N~2 substitution at C‐O with inversion of the configuration. Hydrolysis of __cis__‐ and __trans__‐4,5‐octanesultones 1a‐b under acidic conditions is stereospecific and leads to