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Hydrolytic equilibria of metallic ions—II: The hydrolysis of Fe(II) ion in NaClO4 solutions

✍ Scribed by J.A. Bolzan; A.J. Arvía


Publisher
Elsevier Science
Year
1963
Tongue
English
Weight
671 KB
Volume
8
Category
Article
ISSN
0013-4686

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✦ Synopsis


The acidic ionization (hydrolysis) constant of ferrous ion has been measured in the range of temperature between 20 and 40°C and of ferrous ion concentration between OXtO and O-062 M, in 05 to 2 M sodium perchlorate solution, according to the theory of the constant ionic medium. The value of PK.' obtained at 25°C is 6.74 f O-06. Within experimental error &' is independent of the ferrous ion and sodium perchlorate concentrations, The temperature dependence of K.' is expressed by * Manuscript received


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