Hydrolytic equilibria of metallic ions—II: The hydrolysis of Fe(II) ion in NaClO4 solutions
✍ Scribed by J.A. Bolzan; A.J. Arvía
- Publisher
- Elsevier Science
- Year
- 1963
- Tongue
- English
- Weight
- 671 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
The acidic ionization (hydrolysis) constant of ferrous ion has been measured in the range of temperature between 20 and 40°C and of ferrous ion concentration between OXtO and O-062 M, in 05 to 2 M sodium perchlorate solution, according to the theory of the constant ionic medium. The value of PK.' obtained at 25°C is 6.74 f O-06. Within experimental error &' is independent of the ferrous ion and sodium perchlorate concentrations, The temperature dependence of K.' is expressed by * Manuscript received
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