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Hydrolysis of sulfur trioxide to form sulfuric acid in small water clusters

✍ Scribed by Larson, Laura J.; Kuno, Mayuso; Tao, Fu-Ming


Book ID
121678806
Publisher
American Institute of Physics
Year
2000
Tongue
English
Weight
450 KB
Volume
112
Category
Article
ISSN
0021-9606

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Calculations of the structure of HaSG4, the SOa-Ha0 adduct, and the magnitude of the barrier between them, were made with the CNDO/Z method. The results suggest the importance of small cluster formation in the gas phase reaction of SO3 and HaO, and offer an explanation for its observed rapid rate.