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Gas phase complexes: considerations of the stability of clusters in the sulfur trioxide—water system

✍ Scribed by Paul M. Holland; A.W. Castleman Jr.

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
356 KB
Volume
56
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

Calculations of the structure of HaSG4, the SOa-Ha0 adduct, and the magnitude of the barrier between them, were made with the CNDO/Z method. The results suggest the importance of small cluster formation in the gas phase reaction of SO3 and HaO, and offer an explanation for its observed rapid rate.

* The Cooperative Institute for Research in Environmental

Sciences is jointly sponsored by the University of Colorado and the National Oceanic and Atmospheric Administration.

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