Hydrolysis of Poly(alkylene amidophosphate)s Containing Amino Acid or Peptide Residues in the Side Groups. Kinetics and Selectivity of Hydrolysis

Enantioselective hydrolysis of α-amino a

Enantioselective hydrolysis of α-amino acid esters in the presence of polymer catalysts containing (S)-hydroxyproline groupings and copper(II) or nickel(II) ions

✍ I.A. Yamskov; B.B. Berezin; L.A. Belchich; V.A. Davankov 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 166 KB

Asymmetric polymers containing metal-chelating (S)-hydroxyproline groups in cross-linked polystyrene (I) and acrylamide (ll) matrices were used as catalysts for hydrolysis of or-amino acid esters. The hydrolysis catalysed by polymers I and II, complexed with Cu and Ni ions, displayed in many cases s