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Hydrolysis of Osmium and Ruthenium Carbyne Complexes

✍ Scribed by Chen, Jiangxi; Sung, Herman Ho-Yung; Williams, Ian Duncan; Jia, Guochen


Book ID
126952027
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
374 KB
Volume
30
Category
Article
ISSN
0276-7333

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πŸ“œ SIMILAR VOLUMES


Osmium(II) and Ruthenium(II) Arene Malto
✍ Annaβ€…F.β€…A. Peacock; Michael Melchart; Robertβ€…J. Deeth; Abraha Habtemariam; Simon πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 475 KB

## Abstract Density functional calculations show that aquation of [Os(Ξ·^6^‐arene)(XY)Cl]^__n__+^ complexes is more facile for complexes in which XY=an anionic O,O‐chelated ligand compared to a neutral N,N‐chelated ligand, and the mechanism more dissociative in character. The O,O‐chelated XY=maltola