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Unconventional Mixed-Valent Complexes of Ruthenium and Osmium

✍ Scribed by Wolfgang Kaim; Goutam Kumar Lahiri


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
772 KB
Volume
46
Category
Article
ISSN
0044-8249

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## Abstract Pentanuclear linear‐chain PtPd complexes {[Pt~2~(NH~3~)~2~X~2~(μ‐pivalamidato)~2~(CH~2~COCH~3~)]~2~[PdX′~4~]}·2CH~3~COCH~3~ (X = X′ = Cl (1a), X = Cl, X′ = Br (1b), X = Br, X′ = Cl (1c), X = X′ = Br (1d)) composed of a monomeric Pd^II^ complex sandwiched by two amidato‐bridged dimeric P

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Spectroscopic data for compounds 4±6 are given below; all other information pertaining to the synthetic and computational work is provided in the Supporting Information. Complete crystallographic data for the structural analyses have been deposited with the Cambridge Crystallographic Data Centre. CC