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Hydrolysis of Chloro(silyl)olefins in Neutral and Acidic Media

✍ Scribed by V. G. Lakhtin; V. D. Sheludyakov; P. V. Ivanov; N. P. Telegina; E. A. Chernyshev

Book ID
111608384
Publisher
Springer
Year
2003
Tongue
English
Weight
43 KB
Volume
73
Category
Article
ISSN
1070-3632

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A screen of over 500 diversely functionalized additives in osmium-catalyzed dihydroxylation has uncovered that electron-deficient olefins are converted into the corresponding diols much more efficiently when the pH of the reaction medium is maintained on the acidic side. Further studies have identif