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Hydrolysis of an isolable selenoseleninate under acidic and alkaline conditions

✍ Scribed by Akihiko Ishii; Takeshi Takahashi; Juzo Nakayama


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
114 KB
Volume
12
Category
Article
ISSN
1042-7163

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✦ Synopsis


Abstract

Acid‐catalyzed hydrolysis of a selenoseleninate [TripSe(O)SeTrip](Trip = 9‐triptycyl) in 2 M HClO~4~‐1,4‐dioxane at room temperature yielded the selenenic acid (TripSeOH). Alkaline hydrolysis of TripSe(O)SeTrip gave the diselenide (TripSeSeTrip) and the seleninic acid (TripSeO~2~H), where air oxidations of the resulting selenol (TripSeH) and TripSeOH occur at a considerable rate. Β© 2001 John Wiley & Sons, Inc. Heteroatom Chem 12:198–203, 2001


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