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Hydrolysis of 8-Quinolyl Phosphate Monoester: Kinetic and Theoretical Studies of the Effect of Lanthanide Ions

✍ Scribed by Souza, Bruno S.; Brandão, Tiago A. S.; Orth, Elisa S.; Roma, Ana C.; Longo, Ricardo L.; Bunton, Clifford A.; Nome, Faruk


Book ID
127075242
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
733 KB
Volume
74
Category
Article
ISSN
0022-3263

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## Abstract Quantum chemistry methods coupled with a continuum solvation model have been applied to evaluate the substrate‐assisted catalysis (SAC) mechanism recently proposed for the hydrolysis of phosphate monoester dianions. The SAC mechanism, in which a proton from the nucleophile is transferre