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Hydrolysis and aminolysis of metal ion activated esters. Nucleophilic paths and properties of the tetrahedral intermediate

โœ Scribed by Buckingham, D. A.; Dekkers, J.; Sargeson, A. M.; Wein, M.


Book ID
121302861
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
341 KB
Volume
94
Category
Article
ISSN
0002-7863

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The mechanisms of hydrolysis of thial esters are currently receiving much attention and are of particular interest to bioorganio chemists (1). Such hydrolyses are known to be accelerated by metal ions, especially mercuric and silver ions, but little quantit-