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Hydrogenolysis of the isomeric 1,2:4,6-di-O-benzylidene-α-d-glucopyranose derivatives with the LiAlH4AlCl3 reagent

✍ Scribed by András Lipták; János Imre; János Harangi; Pál Nánási


Book ID
102640243
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
497 KB
Volume
116
Category
Article
ISSN
0008-6215

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Hydrogenolysis of 3,5-0-benzylidene acet
✍ András Lipták; András Neszmélyi; Pavol Kováč; Ján Hirsch 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 447 KB

Abebmt-The hydrogcnolysis of methyl 3,54benzylidene-a-and -/3-D-xylofuranoside derivatives with the LiAII&-AICI, reagent gave S-benzyl ethers as main products. In some cases the attack of the reagent occured at the ring oxygen of the furanoside skeleton to yield SObcnzyI-I-Omethylxylitol derivatives