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Hydrogenolysis of benzylidene acetals of 1,6-anhydro-β-d-galactopyranose derivatives with the LiAlH4—AlCl3 reagent

✍ Scribed by Carmen Subero; Luis Fillol; Manuel Martín-Lomas


Book ID
108308569
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
402 KB
Volume
86
Category
Article
ISSN
0008-6215

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Hydrogenolysis of 3,5-0-benzylidene acet
✍ András Lipták; András Neszmélyi; Pavol Kováč; Ján Hirsch 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 447 KB

Abebmt-The hydrogcnolysis of methyl 3,54benzylidene-a-and -/3-D-xylofuranoside derivatives with the LiAII&-AICI, reagent gave S-benzyl ethers as main products. In some cases the attack of the reagent occured at the ring oxygen of the furanoside skeleton to yield SObcnzyI-I-Omethylxylitol derivatives