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Hydrogen/Deuterium Exchange of Nucleotides in the Gas Phase

✍ Scribed by Robinson, Jessica M.; Greig, Michael J.; Griffey, Richard H.; Mohan, Venkantraman; Laude, David A.

Book ID
126235777
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
108 KB
Volume
70
Category
Article
ISSN
0003-2700

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The gas-phase hydrogen-deuterium exchange of phosphorothioate d(GTCAG) and d(TCGAT) has been examined using electrospray Fourier transform ion cyclotron resonance (FTICR) mass spectrometry. The exchange has been monitored for the [M-2H] 2Γ€ , [M-3H] 3Γ€ , and [M-4H] 4Γ€ charge states. The mole fraction