Hydrogenation without a Metal Catalyst: An ab Initio Study on the Mechanism of the Metal-Free Hydrogenase from Methanobacterium thermoautotrophicum

On the Mechanism of Catalysis by a Metal

On the Mechanism of Catalysis by a Metal-Free Hydrogenase from Methanogenic Archaea: Enzymatic Transformation of H2 without a Metal and Its Analogy to the Chemistry of Alkanes in Superacidic Solution

✍ Prof. Dr. Albrecht Berkessel; Prof. Dr. Rudolf K. Thauer 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 506 KB

I hc kincllc inc~iwi-eiiieiif\ &&ere performed under pseudo-first-oi-dcr conditions a t I M ioiiic ~Ireiiflli (NaNO,). Solutions of the ligand end the coniplexes were hullcred ~i t l i pho\phatl: at pH =7. The rate of the reaction is independent of the pH 111 thi\ irangc ( I ] The p \'iiluc?, for th