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Hydrogenation of coal possessing chemically bonded metals and the use of polystyrene as a model

✍ Scribed by Michael V. McCabe; Milton Orchin

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
442 KB
Volume
55
Category
Article
ISSN
0016-2361

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✦ Synopsis

By applying known techniques for preparing polystyrene-bound transition metal catalysts, both cobalt and tin complexes have been attached to bituminous coal via the metal atoms. Samples possessing the same metals physically adsorbed on the coal were also prepared. All samples were treated at 390Β°C under 13.8 MPa (2000 psi) hydrogen pressure. The metal-bound coal samples gave better liquefaction with less hydrogen consumption than was observed with the samples incorporating adsorbed metals. In order ultimately to provide more information on the role and fate of catalysts in coal hydrogenation, cross-linked polystyrene has been used as a model substrate.

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