✦ LIBER ✦
The Interplay of Hydrogen Bonding and Multiple Metal Binding – A New Cyclic Polyaminopolyalcohol Ligand as Building Block for the Construction of Microporous, Supramolecular Networks
✍ Scribed by Günter J. Merten; Christian Neis; Stefan Stucky; Volker Huch; Eva Rentschler; Harald Natter; Rolf Hempelmann; Klaus Stöwe; Kaspar Hegetschweiler
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 536 KB
- Volume
- 2012
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
✦ Synopsis
Cyclohexane-based polyaminopolyalcohols (PAPAs) such as 1,3-diamino-1,2,3-trideoxy-cis-inositol (daci) have been prepared by hydrogenation of suitable aromatic precursors. The pentanuclear complex [Cu 5 (daci) 4 (H -2 daci) 2 ](SO 4 ) 3 •18H 2 O (C3) revealed antiferromagnetic and ferromagnetic interactions between the Cu II centers with an S = 3/2 ground state.