Manganese(II) is oxidized by ozone in acid solution, k ϭ (1.5 Ϯ 0.2) ϫ in HClO 4 and in H 2 SO 4 . The plausible mechanism is 3 Ϫ1 Ϫ1 3 Ϫ 1 Ϫ 1 10 M s k ϭ (1.8 Ϯ 0.2) ϫ 10 M s an oxygen atom transfer from O 3 to producing the manganyl ion which subse-2ϩ 2ϩ Mn MnO , quently reacts rapidly with to for
Hydrogenation. II. Mechanism of the catalytic reduction of ketones (and enol derivatives) in alcoholic acid solution
✍ Scribed by M. Acke; M. Anteunis
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 417 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0037-9646
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A series of acyclic and cyclic enol derivatives 1 has been transformed into the corresponding α-amino-functionalized ketones 2 by means of enantioselective catalytic aziridination with chiral Cu complexes, prepared in situ from [Cu(MeCN)4]PF 6 and the optically active ligands 3, by using (N-tosylimi
## Abstract The crystal structures of 3‐methylpiperid‐1‐ylmethane‐1,1‐diphosphonic (**2**), 4‐methylpiperid‐1‐ylmethane‐1,1‐diphosphonic (**3**), 2‐ethylpiperid‐1‐ylmethane‐1,1‐diphosphonic (**4**), and 2‐methylpiperid‐1‐ylmethane‐1,1‐diphosphonic (**5**) acids have been determined and are discusse