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Hydrogen peroxide oxidation by catalase-peroxidase follows a non-scrambling mechanism

✍ Scribed by Jutta Vlasits; Christa Jakopitsch; Manfred Schwanninger; Peter Holubar; Christian Obinger


Book ID
118442158
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
112 KB
Volume
581
Category
Article
ISSN
0014-5793

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Hydrogen Peroxide Decomposition by a Non
✍ Willi Sicking; Hans-Gert Korth; Georg Jansen; Herbert deβ€…Groot; Reiner Sustmann πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 874 KB

## Abstract Non‐heme iron(III) complexes of 14‐membered tetraaza macrocycles have previously been found to catalytically decompose hydrogen peroxide to water and molecular oxygen, like the native enzyme catalase. Here the mechanism of this reaction is theoretically investigated by DFT calculations