Fluorescent Probes for Hydrogen Peroxide Based on a Non-Oxidative Mechanism
โ Scribed by Hatsuo Maeda; Yuka Fukuyasu; Shoko Yoshida; Masako Fukuda; Kanako Saeki; Hiromi Matsuno; Yuji Yamauchi; Kenji Yoshida; Kazumasa Hirata; Kazuhisa Miyamoto
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 116 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0044-8249
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๐ SIMILAR VOLUMES
the diarylmethyl cation 1 รพ . The carbocation, which was formed with a rate constant (k i ) of 5 รฎ 10 2 s ร1 was consumed with a rate constant (k TFE ) of 10.4 s ร1 under these conditions (Table 2, entry 15). Analogously, formation and consumption of 1 รพ was observable in other TFE/CH 3 CN mixtures
## Abstract **The first ratiometric** fluorescent probe for hypochlorite has been developed through regulation of the electronโwithdrawing ability of the electron acceptor in an intramolecular chargeโtransfer (ICT) system by a deoximation reaction (see figure; EWG=electronโwithdrawing group).magnif