Hydrogen peroxide and hydroxyl radical formation by methylene blue in the presence of ascorbis acids
✍ Scribed by G. R. Buettner; T. P. Doherty; T. D. Bannister
- Publisher
- Springer-Verlag
- Year
- 1985
- Tongue
- English
- Weight
- 18 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0301-634X
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📜 SIMILAR VOLUMES
The hydroxylation of benzoic acid by hydrogen peroxide initiated b 589 nm radiation is catalyzed by the following Fe(II1) compounds: F:CL K3[Fe(C204) 1, Na2[Fe(CN)5NO], and K3[Fe(CN)6]. This photochemical reac 1' ion can be ef ectivety sensitized by methylene blue. ?
## Abstract Iron complexes (tpa)Fe(OTf)~2~ (1) and (bpmen)Fe(OTf)~2~ (2) [tpa=tris‐(2‐pyridylmethyl)amine; bpmen=__N,N′__‐bis‐(2‐pyridylmethyl)‐__N,N′‐__dimethyl‐1,2‐ethylenediamine] were found to catalyze the __in situ__ formation of AcOOH from H~2~O~2~ and AcOH in the course of olefin oxidations.