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Hydrogen isotope effects in the oxidation of labeled formate in vivo

✍ Scribed by Edward J. Kuchinskas; Antonio Horvath; Julian R. Rachele

Book ID
118842422
Publisher
Elsevier Science
Year
1959
Tongue
English
Weight
229 KB
Volume
81
Category
Article
ISSN
0003-9861

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✍ M. A. Brusa; A. J. Colussi πŸ“‚ Article πŸ“… 1982 πŸ› John Wiley and Sons 🌐 English βš– 400 KB

Rates of oxidation of XCOO-(X = H, D) by Brz in acid aqueous media were measured between 274 and 332 K. The derived Arrhenius parameters for both reactions log k ~( M -l S-') = (11.81 f 0.10) -(14.33 f 0.13)/0 log ~D ( M -' S-') = (13.77 f 0.13) -(17.62 f 0.04)/0 where 0 = 4.575T X kcal/mol, with (