Isotope effect in oxidative nucleophilic substitution of hydrogen in nitroarenes
✍ Scribed by Mieczysław Mąkosza; Krzysztof Staliński
- Book ID
- 108386726
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 122 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Tertiary carbanions generated from a-substituted phenylacetonitriles in liquid ammonia add to nitrobenzenes in the para position to form the corresponding oH-adducts which are transformed, depending on the starting nitriles and the reaction conditions, to products of oxidative nucleophilic substitut
Enolates generated by treatment of silyl ketene acetals and enol ethers with fluoride ion sources add to nitroarenes to produce s H adducts that oxidize either with KMnO 4 to give substituted nitroarenes or with dimethyldioxirane to give substituted phenols. In the latter case the oxidation results