Hydrogen bonds in carbohydrates
β Scribed by V. V. Sivchik; R. G. Zhbankov
- Book ID
- 104879538
- Publisher
- Springer
- Year
- 1990
- Tongue
- English
- Weight
- 450 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1040-0400
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π SIMILAR VOLUMES
The rotational states of hydroxyl groups and the structure of hydrogen bonds in crystals of cc-D-glucopyranose, j?-D-glucopyranose, a-r>-galactopyranose, P-Dgalactopyranose, methyl a-D-altropyranoside,and methyl j?-D-galactopyranoside are predicted by using the atom-atom potential method. Good agree
NMR data (chemical shifts, NOEs, coupling constants and variable temperature experiments), FT-IR data and MM2 Β° molecular mechanics calculations have allowed us to demonstrate that 3-amido-l,6-anhydro-3-deoxy-[~-D-glucopyranose acts as a hydroxyl-based interaction unit and provides conformational co