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Conformational restriction by intramolecular hydrogen bonding. Carbohydrate-carbohydrate self-assembly

✍ Scribed by Manuela López de la Paz; Gary Ellis; Soledad Penadés; Cristina Vicent

Book ID: 104256529
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 267 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00156-1

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✦ Synopsis

NMR data (chemical shifts, NOEs, coupling constants and variable temperature experiments), FT-IR data and MM2 ° molecular mechanics calculations have allowed us to demonstrate that 3-amido-l,6-anhydro-3-deoxy-[~-D-glucopyranose acts as a hydroxyl-based interaction unit and provides conformational control of self-recognition processes by intramolecular hydrogen bonding.

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