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Hydrogen bonding in N-2-hydroxybenzylaniline

✍ Scribed by A.G. Moritz

Publisher
Elsevier Science
Year
1959
Weight
459 KB
Volume
15
Category
Article
ISSN
0371-1951

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✦ Synopsis

The O-H and N-H stretching frequencies of a numbor of N-bcnzylanilines and N-2-hy&oxybenzylanilines have been measured in dilute carbon tetrachloride solution and attempts made to relate the observed spectra to the known effects of substituents.

The results indicate that rotational isomerism probably occurs in the N-benzylanilines and that the intramolecular hydrogen bond in the N-2-hydroxybenzylaniline is responsible for a change in hybridization on the nitrogen atom.

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