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Hydrogen bonding by chloroform-d as a conformational probe of the macrobicyclic diamines

✍ Scribed by R.C. Lord; Mwindaace N. Siamwiza


Book ID
113373589
Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
680 KB
Volume
31
Category
Article
ISSN
1386-1425

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Resorufm is shown to be a good probe solute for the direct measurement of the rates of formation and breaking of solventsolute hydrogen bonds. In ethanol, a hydrogen-bond equilibration time of 40 ps is found for both the ground and excited states. Deuteration of the solvent has no effect on the equi