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Hydrogen bonding as a probe of electron densities: limiting gas-phase nucleophilicities and electrophilicities of B and HX

โœ Scribed by Legon, A. C.; Millen, D. J.


Book ID
126223076
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
374 KB
Volume
109
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


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โœ A.C. Legon; D.J. Millen ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 602 KB

The hydrogen-bond lengths r( B...H-X) and r(B...D-X) have been redetermined on a consistent basis for the axially symmetric dimers B...HX, where B=N2, CO, PHa, HCN, CHsCN, NH,, or (CH3)3N and X=F, Cl or CN. For the series B...HF and B...HCl, the difference in the effective zero-point bond lengths Sr

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The gas-phase hydrogen/deuterium (HID) exchange kinetics of several protonated amino acids and dipeptides under a background pressure of CH3OD were determined in an external source Fourier transform mass spectrometer. H/D exchange reactions occur even when the gas-phase basicity of the compound is s