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Hydrogen Bonding Abilities of Cyclic Sulfoxides and Cyclic Ketones 1

✍ Scribed by Tamres, Milton; Searles, Scott

Book ID
127001689
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
546 KB
Volume
81
Category
Article
ISSN
0002-7863

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An nmr spectral comparison of a model cyclic pentapeptide cyclo(G1y-Pro-Gly-D-Phe-Pro) with an analogous pseudopeptide has been made. The pseudopeptide contains a $[CH2S] amide bond replacement a t the only amide linkage that, in the model, is not involved in an intramolecular hydrogen bond. Both pr