Hydrogen-Bond Acceptance of Bifunctional Ligands in an Alkyne−Metal π Complex
✍ Scribed by Grotjahn, Douglas B.; Miranda-Soto, Valentín; Kragulj, Elijah J.; Lev, Daniel A.; Erdogan, Gülin; Zeng, Xi; Cooksy, Andrew L.
- Book ID
- 127377717
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 71 KB
- Volume
- 130
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
This article outlines the strikingly simple structural pattern to which transition metal complexes containing x-bonding ligands conform, and suggests simple rules (and ligand classifications) by which the pattern can be understood. and by which individual structures can be rationalized or predicted.
A binding pocket for water is created in 1 by the imidazolyl phosphane ligands and the Ru center. Compound 1 proves to be an excellent catalyst for a highly selective anti-Markovnikov hydration of terminal alkynes to give aldehydes rather than isomeric ketones under near-neutral conditions (aldehyde