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Combined Effects of Metal and Ligand Capable of Accepting a Proton or Hydrogen Bond Catalyze Anti-Markovnikov Hydration of Terminal Alkynes

✍ Scribed by Douglas B. Grotjahn; Christopher D. Incarvito; Arnold L. Rheingold

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
95 KB
Volume
113
Category
Article
ISSN
0044-8249

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Combined Effects of Metal and Ligand Cap
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✍ Douglas B. Grotjahn; Christopher D. Incarvito; Arnold L. Rheingold πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 95 KB πŸ‘ 1 views

A binding pocket for water is created in 1 by the imidazolyl phosphane ligands and the Ru center. Compound 1 proves to be an excellent catalyst for a highly selective anti-Markovnikov hydration of terminal alkynes to give aldehydes rather than isomeric ketones under near-neutral conditions (aldehyde

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ChemInform Abstract: Combined Effects of Metal and Ligand Capable of Accepting a Proton or Hydrogen Bond Catalyze anti-Markovnikov Hydration of Terminal Alkynes.
✍ Douglas B. Grotjahn; Christopher D. Incarvito; Arnold L. Rheingold πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 27 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v