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ChemInform Abstract: Combined Effects of Metal and Ligand Capable of Accepting a Proton or Hydrogen Bond Catalyze anti-Markovnikov Hydration of Terminal Alkynes.

✍ Scribed by Douglas B. Grotjahn; Christopher D. Incarvito; Arnold L. Rheingold

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Combined Effects of Metal and Ligand Cap
Combined Effects of Metal and Ligand Capable of Accepting a Proton or Hydrogen Bond Catalyze Anti-Markovnikov Hydration of Terminal Alkynes
✍ Douglas B. Grotjahn; Christopher D. Incarvito; Arnold L. Rheingold πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 95 KB πŸ‘ 1 views

A binding pocket for water is created in 1 by the imidazolyl phosphane ligands and the Ru center. Compound 1 proves to be an excellent catalyst for a highly selective anti-Markovnikov hydration of terminal alkynes to give aldehydes rather than isomeric ketones under near-neutral conditions (aldehyde