Hydrogen Atom Transfer Reactions of C 2- , C 4- , and C 6- : Bond Dissociation Energies of Linear H−C 2 n - and H−C 2 n ( n = 1, 2, 3)
✍ Scribed by Shi, Yang; Ervin, Kent M.
- Book ID
- 127224477
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 120 KB
- Volume
- 112
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
The successive C-H bond dissociation energies of CH,, &Hz. C2H4, and H&O (ketene) are determined using large basis sets and a high level of correlation treatment. For CHI, C2H2, and C2H4 the computed values are in excellent agreement with experiment. Using our results we recommend 107.9 +2.0 and 96.
The gas phase ion/molecule reactions of the title ionic species with carbon suboxide have been studied by ion trap mass spectrometry and interpreted as the result of electrophilic addition of these ions on the electronrich central carbon of C 3 O 2 followed by CO loss.