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Hydrogen atom transfer in the oxidation of hydrogen peroxide by bis(bipyridine)oxo(pyridine)ruthenium(2+) and by bis(bipyridine)hydroxo(pyridine)ruthenium(2+)

✍ Scribed by Gilbert, John; Roecker, Lee; Meyer, Thomas J.

Book ID: 125974677
Publisher: American Chemical Society
Year: 1987
Tongue: English
Weight: 760 KB
Volume: 26
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00254a031

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## Abstract 2,6‐Bis(5‐thioxo‐4,5‐dihydro‐1,2,4‐triazole‐3‐yl)pyridines (**3**, **4**) were used for the first time as ligand in ruthenium catalyzed transfer hydrogenation of acetophenone. The __in situ__ prepared three‐component system Ru(II)/tridentate triamine ligands (**3a**–**3d**, **4a**–**4d*