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Hydrogen abstraction by tert-butoxy radicals. A laser photolysis and electron spin resonance study

✍ Scribed by Paul, H.; Small, R. D.; Scaiano, J. C.

Book ID: 125950766
Publisher: American Chemical Society
Year: 1978
Tongue: English
Weight: 926 KB
Volume: 100
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00482a033

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📜 SIMILAR VOLUMES

Direct measurement of absolute rates of

Direct measurement of absolute rates of hydrogen abstraction by tert-butoxy radicals. A flash photolysis electron spin resonance study

✍ Wong, S. King 📂 Article 📅 1979 🏛 American Chemical Society 🌐 English ⚖ 613 KB

Rate constants for spin trapping tert-bu

Rate constants for spin trapping tert-butoxy radicals as studied by electron spin resonance

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✍ Furimsky, E.; Howard, J. A.; Morton, J. R. 📂 Article 📅 1972 🏛 American Chemical Society 🌐 English ⚖ 281 KB

Additions and Corrections - An Electron

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Electron Spin Resonance Studies of Free

Electron Spin Resonance Studies of Free Radicals Arising from α-Hydrogen Abstraction from Thioethers

✍ E. A. C. Lucken; B. Poncioni 📂 Article 📅 1972 🏛 John Wiley and Sons 🌐 German ⚖ 335 KB

## Abstract On rapporte les spectres de résonance paramagnétique de radicaux libres du type RSCR^1^R^2^, créés par photolyse d'un mélange de __t__‐butylperoxyde et d'un thioéther. Pour les thioéthers cycliques, tétrahydrothiophène et thiopyranne, les spectres indiquent une interconversion rapide

Hydrogen atom abstraction from polypropy

Hydrogen atom abstraction from polypropylene and polystyrene by t-butoxy radical site of radical attack studied by spin trapping

✍ E. Niki; N. Ohto; T. Kanauchi; Y. Kamiya 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 358 KB

In order to elucidate the site of radical attack on polypropylene and polystyrene, the abstractions of hydrogen atoms by t-butoxy radicals and phenyl radicals have been studied by using a spin trapping technique. The r-butoxy radical abstracted tertiary hydrogen atoms selectively from polypropylene,