Hydroformylation of p-substituted styrenes catalyzed by rhodium-triphenylphosphine complexes
β Scribed by Teruyuki Hayashi; Masato Tanaka; Ikuei Ogata
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 435 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0304-5102
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π SIMILAR VOLUMES
The addltlon of formaldehyde to oleflns 1s efficiently catalyzed by RhH2(02COH)[P(l-Pr)3]2 and gives the corresponding aldehydes In neutral solution Transltlon metal complexes exhlblt high reactlvitles toward aldehydes under neutral condo-
SiO 2 -tethered rhodium complexes deriving from Rh(CO) 2 acac and the commercially available 3-(mercapto)propyl-and 3-(1thioureido)propyl-functionalyzed silica gel, respectively, have been used as catalysts in the hydroformylation of some functionalized olefins directed to the preparation of interme