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Hydroformylation of olefins with paraformaldehyde catalyzed by rhodium complexes

✍ Scribed by Tamon Okano; Teruyuki Kobayashi; Hisatoshi Konishi; Jitsuo Kiji

Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
128 KB
Volume
23
Category
Article
ISSN
0040-4039

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✦ Synopsis

The addltlon of formaldehyde to oleflns 1s efficiently catalyzed by RhH2(02COH)[P(l-Pr)3]2 and gives the corresponding aldehydes In neutral solution Transltlon metal complexes exhlblt high reactlvitles toward aldehydes under neutral condo-

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SiO 2 -tethered rhodium complexes deriving from Rh(CO) 2 acac and the commercially available 3-(mercapto)propyl-and 3-(1thioureido)propyl-functionalyzed silica gel, respectively, have been used as catalysts in the hydroformylation of some functionalized olefins directed to the preparation of interme

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## Abstract A new class of substituted tetraphosphine ligands has been applied in the rhodium‐catalyzed regioselective isomerization–hydroformylation of internal olefins. The rhodium/tetraphosphine ligand system is highly effective for the isomerization and hydroformylation of 2‐alkenes to form lin