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Hydroformylation of 1-hexene using polymer-supported rhodium catalysts in supercritical carbon dioxide

✍ Scribed by Shin-Ichiro Fujita; Shuji Akihara; Shinya Fujisawa; Masahiko Arai

Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
517 KB
Volume
268
Category
Article
ISSN
1381-1169

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The stability of a polymer-supported rhodium complex has been studied in a batch process for hydroformylation of 1-hexene, using [Rh(CO)2CI ] 2 as the catalytic precursor and poly(vinylbenzyl diethylenetriamine) as the polymeric ligand. It has been found that the reaction conditions, temperature, pr