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Hydroformylation of 1-hexene and propene with in situ formed rhodium phosphine catalysts

✍ Scribed by Pekka Suomalainen; Heidi K Reinius; Helena Riihimäki; Riitta H Laitinen; Sirpa Jääskeläinen; Matti Haukka; Jouni T Pursiainen; Tapani A Pakkanen; A.O.I Krause

Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
206 KB
Volume
169
Category
Article
ISSN
1381-1169

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Hydroformylation of propene and 1-hexene
Hydroformylation of propene and 1-hexene catalysed by a α-zirconium phosphate supported rhodium-phosphine complex
✍ Magnus Karlsson; Carlaxel Andersson; Jes Hjortkjaer 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 102 KB

The reaction of the amphiphilic ligand {4-[bis(diethylaminoethyl)aminomethyl]diphenyl}phosphine with ␣-zirconium phosphate, of intermediate surface area (24 m 2 g -1 ), provided a phosphine functionalised support in which electrostatic interaction between ammonium groups on the ligand and de-protona