Hydroformylation of 1-hexene by soluble and zeolite-supported rhodium species part II
β Scribed by Mark E. Davis; Jill Schnitzer; Joseph A. Rossin; Dennis Taylor; Brian E. Hanson
- Publisher
- Elsevier Science
- Year
- 1987
- Weight
- 974 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0304-5102
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π SIMILAR VOLUMES
The reaction of the amphiphilic ligand {4-[bis(diethylaminoethyl)aminomethyl]diphenyl}phosphine with β£-zirconium phosphate, of intermediate surface area (24 m 2 g -1 ), provided a phosphine functionalised support in which electrostatic interaction between ammonium groups on the ligand and de-protona
The stability of a polymer-supported rhodium complex has been studied in a batch process for hydroformylation of 1-hexene, using [Rh(CO)2CI ] 2 as the catalytic precursor and poly(vinylbenzyl diethylenetriamine) as the polymeric ligand. It has been found that the reaction conditions, temperature, pr