Hydrodechlorination over Zeolite-Supported Catalysts: Clarification of the Reaction Mechanism
β Scribed by Istvan Hannus; Janos Halasz
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 18 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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Kinetic measurements of the selective catalytic reduction (SCR) of NO by methane were performed over CeO 2 /H-ZSM-5, In-ZSM-5, and CeO 2 /In-ZSM-5 catalysts. The parameter space covered NO, CH 4 , and O 2 concentrations varying from 250 to 1000 ppm, from 500 to 2000 ppm, and from 0.5 to 10 vol.-%, r
The reaction of CO and NH, was performed over M/X (M=Rh, Ru, Pd; X=A1201, SiOz, TiO\*) films. lnfrared spectroscopy was used to monitor the formation of surface intermediates. Isocyanate (NCO) was detected for all of the metals when the support was A1203 or SiO\*, but not for TiOz. The NC0 resided o