๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Hydrocarbons from reactions of 1-halocyclohexenes with potassium t-butoxide. Additional evidence for the intermediacy of 1,2-cyclohexadiene

โœ Scribed by A.T. Bottini; F.P. Corson; R. Fitzgerald; K.A. Frost Jr.


Book ID
104222578
Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
237 KB
Volume
11
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


1-t-butoxycyclohexenes from reactions of
โœ A.T. Bottini; F.P. Corson; R. Fitzgerald; K.A. Frost Jr. ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 215 KB

Compelling evidence indicates that reactions of pbenylllthium in ether at >lOC" with lchlorocyclopentene, 1-chlorocyclohexene (&), and l-chlorocycloheptene occur predominantly, and probably exclusively, by elimination-addition mechanisms involving cycloalkynes.l In marked contrast, equally compellin

Nucleophilic substitution reactions of t
โœ A.T. Bottini; Bruce Anderson ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 246 KB

In 1961, Woli.nslryl described the conversion of m-bromocamphene to a mixture of 2-and 3-tbutoxy-k,k3imethylbicyclo[3.2.l]oct-2-ene effected by potassium t-butoxide (z-BuOK), and he rationalized the reaction on the basis of a bicyclo[3.2.l]oct-2-yne intermediate (1) that adds