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Hydroborierung und Hydrozirconierung von tert-Butylimino-2,2,6,6-tetramethylpiperidino-boran

✍ Scribed by Detlef Männig; Prof. Dr. Heinrich Nöth; Manfred Schwartz; Dr. Siefried Weber; Ulrich Wietelmann


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
250 KB
Volume
97
Category
Article
ISSN
0044-8249

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✦ Synopsis


I51 "Si-NMR: S= -39.70, -7.62 ( = 2 :l). MS (relative Intensitat [Yo]): m/z 350 (50. M+), 335 (19, M-CHI). 277 (54, M-CHI-6ch&Si), 245 (4, M-CH1-6ch+SiS), 73 (100. (CH3),Si).


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✍ Nöth*, Heinrich ;Rattay, Wilfried ;Wietelmann, Ulrich 📂 Article 📅 1987 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 320 KB 👁 1 views

Contributions to the Chemistry of Boron, 184". -Pentacarbonylmctal Complexes of (rert-Butylimino)(2,2,6,~tet~dmethyl- piperidino)borane (tert-Butylimino~2,2,6,6-tetramethylpiperidino)borane (1) reacts with Cr(CO), or W(CO)n under photolytic conditions producing peatacarbonylmetal complexes 2. The M(