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Hydroboration of alkenes and alkynes by 1,3,2-dithiaborolane

✍ Scribed by Thaisrivongs, Suvit; Wuest, James D.


Book ID
126922133
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
720 KB
Volume
42
Category
Article
ISSN
0022-3263

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Rhodium(i)-catalyzed asymmetric hydrobor
✍ Makoto Sato; Norio Miyaura; Akira Suzuki πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 273 KB

Several rhodium(I) complexes containing chiral phosphine, (+) DIOP, (+> BINAP, (S,S) CHIRAPHOS, and (S)(R) BPPFA, have been found to be effective as catalyst for the asymmetric hydrobomtion of pm&h-al alkenes with catecholborane (1,3,2benzodioxaborole) to give optically active 2-alkyl-1,3,2-benzodio