Hydroboration and Organic Synthesis || Synthesis of Alkali Metal 9-Boratabicyclo[3.3.1] nonane (Li, K, and Na 9-BBNH)

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• Book ID: 118135624
• Publisher: Springer Berlin Heidelberg
• Year: 2007
• Tongue: German
• Weight: 124 KB
• Edition: 2007
• Category: Article
• ISBN: 3540490752
• DOI: 10.1007/978-3-540-49076-0_22

✦ Synopsis

9-borabicyclo [3.3.1]nonane, A Commercially Available Reagent, Is The Most Versatile Hydroborating Reagent To Synthesize Organoboranes (b-r-9-bbn). The Reagent Exhibits Remarkable Regio-, Chemo-, And Stereoselectivity During Hydroboration Reactions. The Organoboranes Can Be Converted To C-h, C-o, C-n, C-s, C-halogen, C-metal And Above All C-c Bonds. In Addition, The Suitable Substituted / Unsaturated R Of B-r-9-bbn Can Be Utilized To Produce Dienes, Enynes, Allenes Etc. With Defined Stereochemistry. 9-bbn's Derivatives Have Been Elegantly Used For The Asymmetric Reduction Of Ketone Moiety. Diels-alder And Suzuki Reactions Have Expanded The Utility Of 9-bbn For The Synthesis Of A Variety Of Organic Compounds Required For Industry. Consequently, This Vast Field In The Form Of A Book Will Be Helpful To Synthetic Organic Chemists For Easy Access To Literature, Required For Chemical Transformations.