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Hydrido(methyl)carbene Complex of Platinum(IV)

✍ Scribed by Prokopchuk, Ernest M.; Puddephatt, Richard J.


Book ID
120641702
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
219 KB
Volume
22
Category
Article
ISSN
0276-7333

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The five-coordinate compound [RuHCl(CO)(PiPr 2 Ph) 2 ] (1), [RuHCl 2 (CO)(PiPr 2 Ph) 2 ] -contains the chloro ligands in cis and the phosphanes in trans disposition. The Ru=CH 2 bond which was prepared from RuCl 3 β€’ 3 H 2 O and PiPr 2 Ph in methanol in the presence of NEt 3 , reacts with CO and wit